Abstract
Amorphous phase TiO2 nanotube (NT) arrays as sulfur reservoir are fabricated by anodization method on Ti plate used as current collector. Properties of the NT arrays before heat-treatment are evaluated with those after heat-treatment for applicability as a reservoir and conductor of sulfur electrode. A reasonably high amount of sulfur is loaded (14.8%) from 30% feed sulfur solution at 160 °C in the candidate NT array chosen as the sulfur reservoir. Three electrodes from the only NT array, the sulfur-loaded NT array with and without coating layer are evaluated on electrochemical performances. The sulfur electrode with coating layer, consisting of super-P and PVdF, exhibits the highest initial and retention capacity in discharge, respectively, of 1547 mAh g−1 and 1085 mAh g−1 up to 100 cycles. Rate capability at various C-rates from 0.1 to 30 C is also found to be exceptionally good.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
