Effect of surface acetylation of chitin nanocrystals on the preparation and viscoelasticity of sunflower seed oil-in-water Pickering emulsions

Abstract

Acetylated chitin nanocrystals (ChNCs) were used as stabilizer in this work to prepare sunflower seed oil-in-water emulsions for the morphological and rheological studies. The results revealed that the acetylation with moderate degree of substitution (0.38) reduced hydrophilicity and increased surface charge level of rod-like ChNCs, and as a result, significantly improved the emulsifying ability of ChNCs. At the same oil/water ratio and particle loading, the emulsions stabilized with the acetylated ChNCs had far smaller droplet size (∼3 μm) as compared to the emulsions stabilized with the pristine ChNCs (5–7 μm). The increased droplets numbers and improved surface coating level resulted in the enhanced viscous resistance and yield stress level, which improved the physical stability of the acetylated ChNC-stabilized emulsions as a result. In addition, the droplet clusters easily formed in this system, contributing to weak strain overshoot and decreased large-deformation sensitivity during dynamic shear flow. Therefore, the acetylated ChNC-stabilized system showed enhanced transient stress overshoot during startup flow and weakened thixotropy during cyclic ramp shear flow as compared to the pristine ChNC-stabilized system. The relationships between surface acetylation of ChNCs and flow behavior of emulsions were then established, which provide valuable information on the modulation of the ChNC-stabilized Pickering emulsions.