Effect of sulfur addition and heat treatment on electrical conductivity of barium vanadate glasses containing iron

Abstract

Six glass samples with a composition of 75V 2O 5 + 10BaO + 15Fe 2O 3 mol%, with 0, 10, 15, 20, and 25 wt% of sulfur were prepared by using a quenching method. The samples were measured by XRD, DSC, TEM, Mössbauer spectrometry and D.C. conductivity. The prepared samples were heat treated at temperature close to their crystallization temperatures for 1 h, and then the previous measurements were repeated. The results showed that the treatment process caused the formation of V 2O 5 and FeVO 4 nanocrystals with size of 17–25 nm dispersed in the glass matrix. The addition of sulfur reduced only the vanadium ions to V 4+, while it was found that iron ions were Fe 3+ only. D.C. conduction enhanced due to the small polaron or electron hopping from V 4+ to V 5+ ions. The heat treated samples exhibit much higher conductivity and much lower activation energy than the as-prepared glasses. The heat treated samples showed decreased thermal stability with the addition of sulfur. This considerable enhancement of electrical conductivity after nanocrystallization referred to the formation of extensive and dense network of electronic conduction paths which are situated between V 2O 5 nanocrystals and their surfaces.