Abstract

This paper addresses the relationship between the geology, hydrology, and transient variations in discharge and water chemistry of acidic water discharged by an abandoned underground coal mine: the Majestic Mine in Athens County, Ohio, a partially-flooded, downdip, drift mine. The Middle Kittanning (No. 6) Coal (Allegheny Series, Pennsylvanian System) was mined room-and-pillar until 1921. Loss of support from mine collapse has created large vertical subsidence fractures along the naturally occurring joints within the brittle sandstone overburden. The mine discharge hydrograph, temperature, and pH of the mine discharge indicate that the hydrology of the Majestic Mine can be explained in terms of pseudokarst hydrology. During rainfall events, water is preferentially recharged through the subsidence features. Increased pressure from the mine inflow is transmitted through the flooded workings, causing a rapid increase in discharge, and forcing older mine water out of the mine. A stream draining an overlying watershed is captured by one of the subsidence features, contributing 60 to 80% of the mine water outflow. During the summer, recharge to the mine is negligible because potential evapotranspiration is higher than precipitation. During late summer and fall months, when the mine pool is at its lowest elevation, atmospheric oxygen penetrates back into the mine workings, enhancing the oxidation reactions. During the increased discharge of the spring months, washing of the reaction products from the mine walls produces the highest metals concentrations and chemical loads. *** DIRECT SUPPORT *** A03BX002 00004

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