Effect of strontium chloride on the optical and mechanical properties of γ–glycine crystals

Abstract

AbstractSingle crystals of γ‐glycine have been grown from aqueous solution in the presence of small amount of strontium chloride. Single crystal X‐Ray diffraction analysis was used to measure the unit cell parameters and to confirm the crystal structure. The grown crystals have also been subjected to powder X‐Ray diffraction study to identify the crystalline nature. The presence of all the functional groups of the γ‐glycine has been confirmed by Fourier Transform Infrared (FTIR) spectral analysis. The presence of hydrogen and carbon in the glycine molecules was confirmed by using proton and carbon nuclear magnetic resonance (NMR) spectral analyses. Optical behavior of the crystal was studied using UV – Visible absorbance spectroscopy and second harmonic generation (SHG) studies. The SHG efficiency of γ‐glycine is greater than that of standard potassium dihydrogen phosphate (KDP). Mechanical strength of the γ‐glycine crystal has been determined by microhardness studies. Thermal stability of the grown crystal is probed using thermo gravimetric analysis and differential thermal analysis. Laser damage threshold value has been determined using Q‐switched Nd:YAG laser operating at 1064 nm and with 13 ns pulse width in single shot mode. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)