Abstract
N,N‘-Dicyclohexyl-2,6-naphthalenedicarboxamide (NJS) is an efficient nucleating agent to prepare isotactic polypropylene (iPP) samples rich in the β-modification (β-iPP). However, NJS is not a selective β-nucleating agent, as the related samples always contain both α and β modification of iPP. Depending on the final temperature of heating (Tf), NJS may be partially or completely dissolved in the iPP melt. The dual nucleation ability of NJS was studied by polarized light microscopy (PLM) and calorimetry (DSC). It was established that the lateral surface of the needle crystals of NJS acts as α-nucleating agent. Because of the solubility and dual nucleating ability of NJS, a wide variety of supermolecular structures may form in its presence. The feature of the structure formed during the crystallization of iPP depends on the concentration of the nucleating agent, on the end temperature of heating, and on the thermal conditions during cooling and crystallization. In this study we observed an αβ-transcrystalli...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
