Abstract
The thermal conductivity (TC) of polymers is known to be effectively enhanced by liquid crystallinity. Liquid crystals (LCs) exhibit anisotropic TC with a greater magnitude in the orientation direction. However, the effects of other LC structures than the orientational order, such as smectic layer structures, on TC have not been well studied. This study investigated the correlation between LC structures and thermal diffusivity using a series of LC PMnMA polymethacrylates having azobenzene mesogens in the side chains. PMnMA formed nematic (N), smectic A (SmA), and smectic C (SmC) phases. These LCs were aligned by a magnetic field or large-amplitude oscillatory shear, yielding glassy LC films with mesogen long axes in the in-plane or out-of-plane direction. These glassy LCs increased thermal diffusivities in the LC orientation direction with the degree of LC orientation, whereas N and SmC LCs had smaller values than SmA LCs. These results demonstrated that smectic layers can enhance thermal diffusivity in their normal direction.
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