Effect of SiO2 on microstructure and mechanical properties of composite ceramic coatings prepared by centrifugal-SHS process

Abstract

For high-temperature, sand-bearing, and high-pressure water injection pipelines, failure of commonly used organic epoxy coatings occurs frequently, which needs to be solved urgently. Ceramic coating is excellent alternative to solve this problem, attributed to its high hardness, high temperature resistance, and corrosion resistance. However, ceramic coatings prepared till date suffer from some problems, such as high porosity, and poor toughness. To improve overall performance of composite ceramic coating, herein, ceramic-lined composite steel pipes were synthesized by centrifugal self-propagating high-temperature synthesis (centrifugal-SHS), via doping different concentrations of SiO2 in the Al/Fe2O3 reaction system. The microstructure and phase of composite ceramic coatings after addition of SiO2 were analyzed by optical microscopy with super depth of focus, scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction. Effects of SiO2 on the density and porosity, microhardness and fracture toughness, compression-shear strength and crushing strength of composite ceramic coatings were investigated by Archimedes method, Vickers indentation microfracture method, shearing test, and squeezing test, respectively. Results showed that the introduction of appropriate amount of SiO2 reduced cooling rate of reaction system, thus improving the densification level and strength of coatings. Furthermore, in reaction system, FeAl2O4 phase disappeared, owing to excessive Al, which could improve corrosion resistance of composite ceramic coatings. The optimum doping concentration of SiO2 was found to be 4 wt%, in which composite ceramic coating showed excellent properties.