Effect of sintering temperature and holding time on the microstructure and mechanical properties of ZrB 2–SiCw composites

Abstract

ZrB 2-based ceramic composites containing 20 vol.% SiC whiskers were prepared through hot-pressing. Effect of sintering temperature (1650–1950 °C) and holding time (30–60 min) on the microstructure and mechanical properties of ZrB 2–SiCw composites were investigated. Relative density and grain size increased with increasing temperature, from 93% and 3.0 μm for 1650 °C to 99.5% and 5.6 μm for 1950 °C. Similarly, relative density and grain size increased when the holding time prolonged from 30 min to 45 min, and then showed a little increment with further increase of time. Flexural strength and fracture toughness were improved with hot-pressing temperature increased, except 1950 °C. Analysis suggested that mechanical properties were limited by the thermal instability of SiC whiskers at such high temperature. Meanwhile, flexural strength increased as the increase of holding time. However, no obvious increment was found for fracture toughness, which was probably attributed to the residual pores.