Effect of sintering aids content and powder characteristics on gas pressure sintered Si3N4 ceramics

Abstract

The Si3N4 raw powder, sintering aids, and sintering process are the most critical factors affecting the thermal conductivity and mechanical properties of Si3N4 ceramics. The impact of sintering aids content and powder characteristics on gas pressure sintered Si3N4 ceramics was investigated in this study. Lower aids content facilitated phase transformation prior to densification, promoting a pronounced bimodal microstructure. Based on in-situ shrinkage behavior, liquid phase sintering of Si3N4 ceramics can be divided into three stages without clear boundaries. Between 1200 and 1400 °C, higher oxygen and metallic impurities favored particle rearrangement. Between 1400 and 1800 °C, the dissolution and precipitation process was probably controlled by the α-phase ratio and particle size. Above 1800 °C, subsequent grain growth was primarily facilitated by the Ostwald ripening process, leading to a reduced densification rate. Higher oxygen content leading to greater weight loss during sintering. Higher Fe resulted in a darker color of sintered Si3N4 ceramics. High α-phase content promoted the formation of a bimodal microstructure and ensured superior mechanical properties. Reduced levels of oxygen and aluminum were prerequisites for achieving high thermal conductivity. Powders prepared by silicon nitriding method were cost-effective materials for the preparation of high-performance Si3N4 ceramic substrates.