Effect of Silane on the Active Aging Resistance and Anticorrosive Behaviors of Natural Lacquer.

Abstract

Environmentally friendly and renewable hybrid lacquer coatings with excellent aging resistant and anticorrosion properties were studied. The coatings were prepared using raw lacquer coupled with the silane agent 3-aminopropyltriethoxysilane or N-(2-aminoethyl)-3-aminopropyltrimethoxysilane via an eco-friendly sol–gel preparation process. The physical–mechanical properties, thermal stability, aging resistance, and anticorrosion properties of the as-prepared coatings were analyzed. Additionally, the surface of the coatings before and after an accelerated aging treatment was studied by scanning electron microscopy and X-ray photoelectron spectroscopy. The results revealed that the hybrid lacquer coating A (with a raw lacquer-to-APTES mass ratio of 1.8:1) resulted in films with a significantly enhanced antiaging effect (e.g., six times higher than that of lacquer at a gloss loss rate of 30%). Besides, this film revealed an exceptional anticorrosion performance (with the lowest corrosion current Icorr = 2.476 × 10–10 A·cm–2) and a high protection efficiency (99.99 and 94.10%), as demonstrated by its electrochemical characteristics. Furthermore, all films exhibited a good barrier because of their dense structure, which prevents the corrosive medium from penetrating the coating during the salt spray test analysis after 1000 h. And the coating A relatively layered was distributing any significant cancaves, integrity better than all coatings studied, indicating that the based electrolyte was easier to penetrate it after salt spraying 2000 h.