Abstract
Effect of Chloride, Nitrate, Bromide and Iodide anions of Potassium on the critical micellar concentration of a non-ionic surfactant Pluronic F108 was determined by using UV–visible spectroscopy. Dye-micellization method was adopted using the diazo dye, Trypan blue. The influence of the above mentioned salts on the surfactant structures, concentration and working experimental condition at the cmc were evaluated and discussed. The micellization was observed to occur at lower concentration in presence of the above salts. The influence of the above salts on cmc was characterized using UV- spectrophotometry, fluorimetry, dynamic light scattering, fluorescence lifetime and cloud point studies. It was noticed that the salts affect the aggregation process consistent with the Hofmeister series with the Chloride, the Nitrate, the Bromide and the Iodide ions coming in decreasing order. Trypan blue has been used, probably for first time as a probe for UV- spectroscopy and fluorimetry analysis in surfactant system.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
