Abstract

Amorphous poly(ethylene oxide) (aPEO) is prepared by the oxy-methylene linkage of PEG400 and complexed with NaI and NaClO 4 with a range of stoichiometries, aPEO x NaAn,x=15-150. Transmission IR spectra and X-ray diffraction data indicate that the aPEO and all salt complexes prepared are amorphous at ambient temperature. A broad conductivity minimum is obtained at low salt concentrations for each complexe series. Ionic conductivities on the order of 10 -4 -10 -5 S/cm were observed at ambiant temperature

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