Effect of Resveratrol on physicochemical structure evolution of lignite during spontaneous combustion

Abstract

Studying the evolution of the physicochemical structure of coal during coal spontaneous combustion (CSC) by antioxidants is of great significance for revealing the mechanism of CSC and preventing it. The effects of three concentrations of Resveratrol (RES) on the physicochemical structure evolution of coal during the low-temperature oxidation (L-TO) process of CSC were comprehensively analyzed through low-field nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) experiments. The results showed that the pore cracks in the coal develop more fully with the increase in oxidation temperature. Besides, there was an increase in porosity and permeability, and a full development of pore throat. Based on the T1-T2 2D fluid identification results, it was found that as the oxidation temperature increased, the adsorption capacity and permeability of the coal were stronger. RES can effectively inhibit the CSC process of coal, with a maximum reduction of 23 % in porosity and a maximum reduction of 82 % in permeability. The hydroxyl groups and CH3/CH2 of coal samples treated with RES decreased by a maximum of 42 % and 43 %, respectively. The oxygen-containing functional groups increased by a maximum of 77 %. RES can not only cover on the coal surface to prevent oxygen from seeping into the coal, but also infiltrate into the pores of coal to inhibit the combination of the active functional groups and oxygen molecules.