Effect of residual stress on azo dye degradation capability of Fe-based metallic glass

Abstract

Fe-based metallic glasses (MGs) are among the most interesting in the area of MG materials, due to their superior properties such as high degradation capability of azo dyes. However, the ways that factors influence the degradation capability of MGs towards azo dyes are still unclear. From this reason, the effect of residual stress on degradation capability of Fe-based MG was investigated. (Fe73.5Si13.5B9Nb3Cu1)91.5Ni8.5 as-cast MG ribbons and annealed MG ribbons were prepared and subjected to degrade Orange II solutions. The as-cast ribbons completely degrade the azo dye within 60min, the ribbons annealed at 673K take 120min, although the annealed ribbons still sustain metastable glassy state. Surface morphology and magnetic domain pattern of the ribbons were characterized carefully. The results demonstrate that the inhomogeneous residual stress could contribute to high degradation capability of the as-cast MG ribbons by generating stress gradient cell and increasing active sites. Therefore, increasing residual stress can be a novel clue to enhance degradation capability of materials.