Abstract
The superconducting properties of Bi1.7Pb0.3Sr2Ca2−xRx(R = Eu, Yb and Ag)Cu3OY have been investigated by X-ray diffraction, electrical resistance and the peritectic transition of these superconductors was studied kinetically under different atmospheres and temperature gradients. X-ray diffraction results show that the volume fraction of the high-Tc (2 2 2 3) phase decreases and that of the low-Tc (2 2 1 2) phase increases as Eu, Yb and Ag concentrations increase. The resistivity measurements reveal that the Tc onset decreases down to 100 K for Eu, 85 K for Yb and 106 K for Ag concentrations. These results are explained on the basis of possible variations of hole concentration with trivalent rare earth ion substitutions. Activation energies and frequency factors for crystallisation were determined by non-isothermal differential thermal analysis (DTA), employing different models. It was found that both peritectic transition and reaction rate were dependent on the ambient atmosphere. Kinetic studies under different atmospheres revealed that the thermal stability of Bi-2 2 1 2 phase was greatly enhanced under oxygen atmosphere.
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