Effect of pro-oxidant concentration on characteristics of packaging films of cobalt stearate filled polypropylene

Abstract

Abstract In this work, polypropylene (PP) filled with different proportions of CoSt were prepared in a twin-screw extruder by compounding technique. Eight films of these compounds were prepared using compression moulding. The modified PP films were characterized for chemical, physical, thermal, and morphological properties (before and after biodegradation). The biodegradation of the CoSt filled PP films was studied under controlled composting conditions, and the degradation intermediates were evaluated for their ecotoxicological impact. The CoSt present in the PP film was confirmed by Fourier transform infrared spectroscopy. As the addition of CoSt was progressively increased, the tensile strength and thermal stability decreased as shown by UTM and thermogravimetric analysis. The compounding of CoSt in PP reduced its crystallinity as revealed by the differential scanning calorimetry and X-ray diffraction analysis, and this led to enhanced degradation of PP. After biodegradation, SEM results of modified PP films showed rougher morphology than before biodegradation. The maximum biodegradation (19.78%) was shown by the film having 2 phr CoSt. The ecotoxicity tests of the degraded material, namely, microbial test, plant growth test, and earthworm acute-toxicity test demonstrated that the biodegradation intermediates were nontoxic. Hence, CoSt filled PP has high industrial potential to make biodegradable flexible packaging.