Effect of Processing Temperature on Gelation and Physical Properties of Low Density TEOS Based Silica Aerogels

Abstract

In the present paper the experimental results of the effect of sol-gel processing temperature on the physical properties of the TEOS based silica aerogels are reported and discussed. The aerogels were produced by the two step sol-gel process at various temperatures in the range of 26–70∘;C followed by supercritical drying using methanol solvent extraction. A remarkable reduction in the gelation time was observed from three and a half days at room temperature to a mere 18 hours at 50∘;C. The best quality aerogels in terms of low density and high optical transmission were obtained for 6 hours hydrolysis time. The aerogels were characterized by the measurements of bulk density, volume shrinkage, porosity, refractive index and optical transmission. Monolithic aerogels with ultra low density (∼0.018 g/cm3), extremely high porosity (∼99%) and optimum optical transmission at 700 nm (∼75%) were obtained for the molar ratio of TEOS:MeOH:acidic water:basic water at 1:99:10.42:14.58 respectively.