Effect of process conditions on co-liquefaction kinetics of waste tire and coal

Abstract

Thermal and catalytic liquefactions of waste (recycled) tire and coal were studied both separately and using mixtures with different tire/coal ratios. Runs were made in a batch tubing bomb reactor at 350–425°C. The effect of hydrogen pressure on the product slate was also studied. Mixtures of tire components and coal were used in order to understand the role of the tire as a solvent in co-liquefaction. In the catalytic runs, a ferric-sulfide-based catalyst impregnated in situ in the coal was used. Both the tire components and the entire tire exhibit a synergistic effect on coal conversion. The extent of synergism depends on temperature, H 2 pressure and the tire/coal ratio. Experiments with coal and tire components show that the synergistic effect of tire is due to the rubber portion of the tire and not the carbon black. The synergism mainly leads to an increase in the yields of asphaltenes, which are nearly double those in the coal-only runs at 400°C. The conversion of coal increases dramatically using the catalyst, but the catalytic effect is attenuated somewhat in the presence of tire, especially at high tire/coal ratios. The data were analyzed using a consecutive reaction scheme for the liquefaction of coal to asphaltenes and thence to oil+gas, both reactions being of second order; a second-order conversion of tire to oil+gas; and an additional synergism reaction when both coal and tire are present, first-order in both coal and tire. Parallel schemes were assumed for thermal (uncatalyzed) and catalyzed reactions. The uncatalyzed liquefaction of coal has a low apparent activation energy, 36 kJ/mol, compared to those for the synergism reaction (84 kJ/mol) and the catalytic coal liquefaction (158 kJ/mol). The conversion of asphaltenes to oil+gas is relatively independent of temperature and of the presence of the catalyst. The catalyst appears to play a significant role in the conversion of coal to asphaltenes, but a negligible role in the synergism reaction.