Effect of preparation method on sinterability and properties of nanocrystalline MgAl2O4and ZrO2-MgAl2O4materials

Abstract

Nanocrystalline MgAl2O4 and ZrO2-MgAl2O4 powders were synthesised by combustion and conventional solid state reaction routes. The synthesised powders were processed, dry pressed, and sintered for 3 h at temperatures ranging from 1550 to 1625°C. The sintered pellets were then characterised in terms of phase (XRD), microstructure (SEM), relative density, apparent porosity, water absorption, hardness, three point bend strength, and fracture toughness. The XRD studies revealed that ZrO2 was present in tetragonal form in the case of combustion synthesised powders (CSP), whereas in powders obtained by solid state reaction (SSP) it was present in the monoclinic form. This study also revealed that the addition of ZrO2 improved the mechanical properties of sintered MgAl2O4 samples: 20 wt-%ZrO2-MgAl2O4 composites prepared from CSPs and conventional SSPs and sintered at 1625°C for 3 h had fracture toughness of 5·96 and 4·33 MPa m1/2 and three point bend strength of 269 and 98 MPa respectively. Higher sintered density, the presence of tetragonal zirconia as a major phase, and the finer microstructure are probably responsible for the superior mechanical properties exhibited by sintered CSP materials as compared with the sintered SSPs.