Abstract

AbstractCu2ZnSnS4 (CZTS) is paid attention to the low‐cost and nontoxic solar cell material. In this study, CZTS thin film was deposited by using an electrodeposition technique followed by a sulfurization after preheating the deposited metallic precursor layer. We investigated the film properties of CZTS thin films for understanding the effect of preheating time on the photovoltaic properties such as carrier lifetime and recombination mechanism by using a microwave photoconductivity decay (μ‐PCD) and a photoluminescence (PL) measurement. The results of the μ‐PCD measurements showed that carrier lifetime increased with increasing the preheating time and longer carrier lifetime was observed in a part of deposited thin film. The PL measurements showed the peak energy shift to lower energy region by a surface position of the sample preheated for 150 min. We found the CZTS crystal quality improved but the homogeneity worsened with increasing the preheating time. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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