Effect of pre-exposure to chloride environment on the tensile deformation of SS 304HCu at 973 K

Abstract

Listen

Translate article

304HCu austenitic stainless steel (SS 304HCu) with 3 % copper content is utilized as the tubing material for advanced ultra-supercritical boilers, which operate at temperatures around 973 K and a pressure of 31 MPa. The current investigation aimed to examine the influence of prior exposure to an acidic chloride environment on the tensile characteristics of SS 304HCu at 973 K with the nominal strain rate of 1× 10−3 s−1 in solution annealed as well as thermally aged (973 K/10000 h) conditions. In the prior exposure condition, both the solution annealed and aged specimens were subjected to a pre-determined potential of −0.14 V (Ag/AgCl) for 48 h in 5 M NaCl + 0.15 M Na2SO4 + 2 ml HCl solutions. Thermally aged SS 304HCu showed lower strength in both true UTS and true yield strength compared to the solution annealed specimen tested at 973 K. Exposure to an acidic environment resulted in a considerable reduction in tensile strength and uniform plastic strain. For all the conditions, saturation-stress-based relationship was employed to describe the flow behaviour of the alloy. The relationship adequately fits the true stress-true strain data of SS 304HCu. A systematic variation in strain hardening parameters with respect to different test conditions is noticed. In the case of the aged alloy, the observed microstructure revealed the presence of M23C6 at grain boundaries and copper precipitates in the grain interior. The increased chromium depletion and the higher degree of sensitization led to the formation of localized pits in pre-exposed aged specimen conditions. Consequently, the synergistic influence of precipitation and pitting corrosion significantly affected the tensile deformation behaviour of SS 304HCu alloy in the aged and pre-exposed condition compared to the solution annealed condition.