Abstract

Effective water management increases the performance of proton exchange membrane fuel cells (PEMFCs). The liquid droplet movement mechanism in the cathode channel, the gas-liquid two-phase flow pattern, and the resulting pressure drop are important to water management in PEMFCs. This work employed computational fluid dynamics (CFD) with a volume of fluid (VOF) to simulate the effects of two operating parameters on the liquid water flow in the cathode flow channel: Gas diffusion layer (GDL) pore shape for water emergence, and distance between GDL pores. From seven pore shapes considered in this work, the longer the windward side of the micropore is, the larger the droplet can grow, and the duration of droplet growth movement will be longer. In the cases of two micropores for water introduction, a critical pore distance is noted for whether two droplets coalesce. When the micropore distance was shorter than this critical value, different droplets coalesce after the droplets grew to a certain extent. These results indicate that the pore shape and the distance between pores should be accounted for in future simulations of PEMFC droplet dynamics and that these parameters need to be optimized when designing novel GDL structures.

Highlights

  • After the liquid water enters the channel through the pores, small spherical droplets form on the surface of the Gas diffusion layer (GDL) and continue to grow

  • The effect of surface tension is much greater than the other forces, which explains why liquid water forms near-spherical droplets on the surface of hydrophobic GDLs

  • The current results provide a guide for effective water management of the proton exchange membrane fuel cell when considering new GDL materials

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. Proton exchange membrane fuel cells (PEMFCs), as a clean, efficient, and environmentally friendly energy generation device, have been used in the fields of transportation, aerospace, and communication [1]. High cost and short life still limit the commercialization of fuel cells [2,3]. The transport and removal of water is critically important to the performance, stability, and durability of the fuel cell [4]. An important water management issue is the gas–liquid flow as water enters the reactant flow field channels, typically mini-channels [5]

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