Effect of polyvinylpyrrolidone and lithium chloride composite desiccant-coated heat exchangers on dehumidification studies

Abstract

Cooling systems are necessities that remain energy intensive, particularly in tropical regions with elevated humidities and temperatures. Conventional vapor-compression air-conditioners are often inefficient because the sensible and latent heat loads are intrinsically coupled. To realize more energy-efficient cooling, solid desiccant-coated devices can be introduced to mitigate the latent heat load. Among such devices, desiccant-coated heat exchangers (DCHEs) are attractive for enabling nearly isothermal dehumidification. Hence, desiccants with high sorption capacity and rapid kinetics are essential. Solid polymeric desiccants are well-positioned to meet these requirements but comprehensive studies on the dehumidification performance of solid polymeric desiccant-coated heat exchangers are currently lacking. In this study, we investigated the potential of polyvinylpyrrolidone (PVP) and lithium chloride (LiCl) composites as desiccant materials at both material and system levels in terms of gravimetric water uptake. Specifically, LiCl is a hygroscopic salt bound by the moisture-sorbing PVP matrix. This work also demonstrates how the Elovich model accurately predicted the PVP-LiCl composite’s sorption kinetics. The results show that the optimum PVP-LiCl composite ratio is 66.7 wt%, with an equilibrium sorption capacity of 280 % at 75 % RH and 25 °C, compared to 29 % for silica gel under the same condition. With much superior sorption kinetics and capacity, the PVP-LiCl-coated prototype heat exchanger demonstrated a moisture removal capacity eight times higher than a silica gel-coated one under dynamic flow towards energy savings in air-conditioning systems.