Abstract
In this study we utilized X-ray diffraction, transmission electron microscopy (TEM) and various types of simple shear flow experiments to investigate the effect of the polar-polar interaction between ethylene-vinyl acetate co-polymers (EVA) and organo-silicates on the nanoscale structures and rheological properties of their melt blends. The WAXS intensities and TEM micrographs demonstrate that the exfoliation and the intercalation of nanoclays respectively prevail in EVA/Cloisite 30B nanocomposites and EVA/Cloisite 15A nanocomposites, respectively. The master curves obtained from transient shear flow tests and their Arrhenius plot demonstrate the formation of side-tethered structure in the melt blends of EVA/ Cloisite 30B nanoclay. Finally, by means of performing a series of large-strain relaxation tests and regression techniques, the single integral Wagner model, that is expected to appropriately describe the rheometric experiment data of melt blends, was established, and then a comparison of the calculated and measured viscosity and first normal stress is presented.
Published Version
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