Abstract
In this study, we investigated the oxygen evolution reaction (OER) characteristics of Ni–Zn–Fe electrodes by varying plating current density and Ni:Fe ratio in a plating bath. The activity of the OER increased up to the plating current density of 160 mA/cm2, as the Fe content of the deposited electrode increased and electrochemical surface area (ECSA) increased after Zn dealloying. However, for the plated electrode with higher than 160 mA/cm2 of current density, the change in composition caused by underpotential deposition led to decreased activity due to decreasing Fe content and diminishing Zn dealloying. Moreover, when the Ni:Fe ratio in the plating bath was varied, outstanding OER activity was observed at Ni:Fe = 2:1. When the Fe content of the bath increased beyond this ratio, Fe could not restrain Ni oxidation and formed Fe oxides in OER reaction, and oxygen vacancy decreased. These caused a degradation of the OER activity.
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