Effect of physical aging on tensile stress relaxation and tensile creep of cured EPON 828/epoxy adhesives in the linear viscoelastic region

Abstract

AbstractThe effect of physical aging on viscoelastic properties was studied for several cross‐linked epoxies in the glassy state. Tensile creep and tensile stress relaxation were measured during isothermal physical aging, following rapid quenching of samples annealed above the glass‐transition temperature (Tg). The momentary creep curves measured at 21°C, 45°C, and 61°C below Tg for different epoxies could be fitted to an empirical equation for the creep compliance D(t): Values for β and to were obtained, and the dependence of to on the aging time was determined. Shift factors were calculated to investigate changes in molecular mobility during physical aging. The momentary stress relaxation was measured on the same epoxy materials as used for the creep studies. The stress relaxation curves were fitted to the following equation for the tensile modulus E(t): Values for α and to were obtained. The influence of physical aging on‐to was again studied by calculating shift factors as a function of the aging time. The results are compared with the results of the creep tests and discussed in the context of current molecular theories of physical aging of glassy polymers.