Effect of phenol concentration on the photocatalytic performance of ZnO nanoparticles

Abstract

AbstractBACKGROUNDPhenol and its derivatives are considered toxic compounds, even at low concentrations. Their accumulation in water effluents has become a serious problem that could be resolved by using zinc oxide (ZnO)‐based photocatalysts.RESULTSZnO nanoparticles were synthesized through the precipitation method, using zinc nitrate and sodium carbonate as reagents. The as‐synthesized powder was calcined for 4 h at 500 °C (2° C min−1). X‐Ray diffraction analysis confirmed a hexagonal crystalline phase (wurtzite) with an average crystallite size of 38 nm. The Kubelka‐Munk method was used to determine a band gap of 3.27 eV through UV–Vis diffuse reflectance spectrum and a Brunauer‐Emmett‐Teller (BET) specific area of 12 m2 g−1 was obtained from N2 adsorption analysis. The photocatalytic activity of ZnO was evaluated under visible light (300 W) lamp, with 1 mg mL−1 of photocatalyst and using phenol solutions at different concentrations of 5, 10, 25, and 50 ppm; the obtained degradation percentages were 98%, 97%, 94%, and 71%, respectively. Three cycles were performed with the ZnO used in the reactions with phenol at 5 and 50 ppm, decreasing the degraded percentages to 87% and 65%, respectively. The generation of hydroxyl radicals was estimated for the ZnO and ZnO samples after three cycles by means of fluorescence spectroscopy analysis. It was observed that the first‐used ZnO material generated a significant amount of hydroxyl radicals.CONCLUSIONWhen compared to ZnO after three cycles of reaction, the amount of generated hydroxyl radicals decreased. It was observed that the higher the amount of phenol, the lower the generation of hydroxyl radicals after reuse; this was probably due to the presence of some adsorbed by‐products of the photocatalytic reaction on the surface of ZnO, as the FTIR spectrum of the post‐reaction sample showed. © 2023 Society of Chemical Industry (SCI).