Abstract
Two kinds of nanocrystalline indium tin oxide (ITO) powders with different crystal structures—rhombohedral and cubic—were prepared using a coprecipitation process through the control of aging time of precipitates after coprecipitation. The densification characteristics of the two ITO powders were examined. During sintering the rhombohedral ITO, which is a high‐pressure phase, was transformed to cubic around 900°C. The phase transformation induced coarsening of grains and many voids in the microstructure retarded densification. On the other hand the cubic ITO, which did not experience phase transformation during sintering, was well densified as the sintering temperature increased. Poor densification of the rhombohedral ITO powder is explained from the viewpoint of coarsening of grains during the phase transformation. This result shows the significance of phase transformation during sintering.
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