Effect of Pd additions on phase stability and hydrogen-induced internal friction of TiZrCuNi glassy alloys

Abstract

The effects of additions of Pd below 10 at.% on the stability and hydrogen-induced internal friction behavior of Ti 34 Zr 11 Cu 47 Ni 8 glassy alloys have been investigated. Thermal analyses indicate that the supercooled liquid region decreases distinctly with increasing Pd content. It was found that internal friction peak temperatures of Ti 34 Zr 11 Cu 47 Ni 8 –Pd hydrogenated glassy alloys (HGAs) in the hydrogen content range below approximately 30 at.% H were higher than those of the original Ti 34 Zr 11 Cu 47 Ni 8 HGAs, especially at hydrogen contents below ∼10 at.% H. It was also found that the internal friction peaks of Ti 34 Zr 11 Cu 47 Ni 8 –Pd HGAs increased with increasing hydrogen content below ∼15 at.% H, after which they tended to saturate. These results are in contrast to the effects of Si addition as previously reported. The effects of Pd are discussed from the viewpoint of the interstitial site distribution for hydrogen and local atomic structure of the glassy alloy.