Effect of Oxygen Concentration on the Oxidative Thermodynamics and Spontaneous Combustion of Pulverized Coal.

Abstract

Spontaneous combustion of pulverized coal has become a safety topic and has been extensively researched. This study using differential scanning calorimetry investigated the exothermic characteristics and spontaneous combustion risk of three metamorphic pulverized coal samples during oxidative combustion, for oxygen concentrations of 21, 19, 17, 15, 13, 11, 9, 7, and 5 vol %. Results indicated that decreased oxygen concentrations reduced exothermic intensity and substantially increased ignition temperatures. The oxidative thermal release observed during the combustion stage was conspicuously higher than during the low-temperature oxidation stage. Thermal release during low-temperature oxidation was low during low oxygen concentrations; however, when the oxygen concentration was less than 13.0 vol.%, it had a considerable influence on exothermic combustion. When the oxygen level was lowered from 21.0 to 5.0 vol %, spontaneous combustion risk indexes lessened from 2.07 (sample A), 1.85 (sample B), and 0.81 [J/(mg min °C2)] (sample C) to 1.08 (sample A), 1.13 (sample B), and 0.40 [J/(mg min °C2)] (sample C), respectively. Both apparent activation energy and spontaneous combustion risk indexes of the samples decreased saliently as oxygen concentration decreased. Thus, reducing oxygen concentration would be an effective method of inhibiting or possibly even preventing the spontaneous combustion of pulverized coal.