Abstract

Hot dipping Zn-Al-Mg coatings were prepared by rapid induction heating combined with gas protection. The influence of oxide scale on the structure and surface quality of a hot-dip Zn-6Al-3Mg alloy coating was studied in this paper. The results showed that the reaction of Fe-Al was suppressed by the scale on the surface of the steel plate. When the thickness of scale was 10 μm and the steel entry temperature was 900 °C, the surface quality of the coating was good. The Zn-Al-Mg coatings mainly consisted of the ternary eutectic structure of Zn/Al/MgZn2 and Fe4Al13 at the interface. When the scale thickness was 2–3 μm with the same steel entry temperature, the surface quality of the coating was poor, and serious stripe-like protrusion defects were formed on the surface of the coating, which was mainly caused by the Fe4Al13 phase separating from the substrate / coating interface into the overlay.

Highlights

  • Steel undergoes corrosion when exposed to different environments

  • The phase structures of the Zn-6Al-3Mg alloys were examined by X-ray diffraction 3(XRD; D8 of 14

  • The phase structures of the Zn-6Al-3Mg alloys were examined by X-ray diffraction (XRD; Advance, Bruker, Germany) at 25 ◦Hot

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Summary

Introduction

Hot-dip galvanizing and its alloy coatings are widely used in steel protection [1]. Solvent method is used in the traditional hot-dip galvanizing alloy process, to obtain a clean surface that is beneficial to the combination of the alloy bath and the steel matrix by pickling the steel plate [19]. Researchers have conducted a series of studies on hot dip galvanizing by the reduction method, and found that the composition of oxide scale of hot-rolled steel with different ingredients was different, leading to the great difference in the reduction process [23,24,25,26,27,28]. Some studies have paid attention to the microstructure of coatings obtained by hot-dip Zn and Zn-Al alloys after a reduction of hot-rolled steel sheets. The environmental pollution caused by the acid pickling of the pre-treatment process and the evaporation of the solvent during the hot dipping process was avoided by this technology

Characterization and Property Evaluation
Results and Discussion
Phase Structure of Steel Plate before Hot Dipping
Surface Appearances and Phase Structure of the Coating
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Asthe cansurface be seenof from
XRD pattern of alloylayer layer on of the at SET 900
Conclusions

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