Abstract

The oxidation of single-crystal and polycrystalline lead sulfide was studied as a function of process duration and temperature. The phase changes during oxidation were followed by thermal analysis, x-ray diffraction, and x-ray photoelectron spectroscopy. The transport properties of as-grown and oxidized PbS layers were measured. A mechanism was proposed for the bulk and surface processes resulting in the formation of photosensitive PbS-based structures.

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