Abstract

The composite photocatalyst with layered nanoarray structure, CdS-sensitized ZnO nanorod arrays (ZnONRA/CdS) grown on ordered TiO2 nanotube arrays (TiO2NTA), was constructed. The performance of composite photocatalyst toward to hydrogen production from water splitting was investigated. The ZnONRA/CdS composite photocatalyst with the substrate layer of ordered TiO2NTA has the enhanced rate of hydrogen production and the improved photostability. It may be attributed to the one-dimensional structure of TiO2NTA at the bottom of ZnONRA/CdS composite photocatalyst, which provides a direct transfer pathway of photoinjected electrons along the photoanode to enhance charge-collection efficiency and consequently reduce electron–hole recombination.

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