Abstract

Sintering behaviors of (Pu0.3U0.7)O2.00 and (Pu0.3U0.7)O1.99 were investigated in controlled oxygen potential. Measurements of shrinkage rate were conducted with a dilatometer. The oxygen potential was adjusted to maintain the constant O/M value of the specimen during the measurements. Based on the shrinkage curves, sintering apparent activation energy was estimated by the master sintering curve method and the constant heating rate method. Microstructures of the sintered specimens were also observed using optical microscopy. The densification behavior of (Pu0.3U0.7)O2 and (Pu0.3U0.7)O1.99 differed considerably. The activation energy for (Pu0.3U0.7)O1.99 was much higher than that for (Pu0.3U0.7)O2.00. Grain growth rate of (Pu0.3U0.7)O2.00 was larger than that of (Pu0.3U0.7)O1.99, however, (Pu0.3U0.7)O2.00 ultimately obtained a lower theoretical density than (Pu0.3U0.7)O1.99.

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