Abstract
Duplex stainless steels were gas tungsten arc welded without filler material in various Ar–N2 mixed gas atmospheres. Weld metals having different nitrogen contents were annealed at 900–1300 K to examine the single effect of nitrogen on the σ transformation. Nitrogen content of the weld metal did not influence the nose temperature and the time for σ initiation in time–temperature–precipitation diagrams for σ, but did decrease the σ content after annealing for long times. These results were correlated with the nitrogen content and microstructure of the weld metals. The effect of σ on the fracture toughness of the weld metal was evaluated by the small punch (SP) test. A small amount of σ in the weld metal led to a marked decrease in the SP energy.
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