Effect of NaCl concentration on the dispersion, stability and rheological properties of MWNTs by CMC

Abstract

A detailed study of the dispersion, rheological and adsorption behaviors between multi-walled carbon nanotubes (MWNTs) and sodium carboxymethylcellulose (CMC) at different NaCl concentration were presented. The experimental results suggested that NaCl concentration governed the dispersion and stability of MWNTs. A small amount of NaCl was contributed to the dispersion and stability of MWNTs, while as the NaCl concentration increased, the MWNTs formed aggregates and the MWNTs suspension became unstable. Adsorption amount, Raman spectroscopy, zeta potential, and adsorption conformation were investigated systematically to elucidate the mechanism of this interesting phenomenon. Surprisingly, results from thermogravimetric analysis (TGA) shown that adsorption amount of CMC on MWNTs didn’t change under any circumstances. The value of zeta potential increased slightly at first and then dropped sharply as the increasing of NaCl concentration. The microstructures were measured by TEM. It was found that uniform CMC adsorption layers were formed on the surface of MWNTs at low NaCl concentrations. However, for the high-salt solution, the MWNTs were wrapped by CMC agglomerates, resulting in poor dispersion stability.