Effect of Na 2CO 3 on hexagonal boron nitride prepared from urea and boric acid

Abstract

Formation of hexagonal boron nitride (hBN) from a precursor obtained by the reaction of urea and boric acid was studied in nitrogen, ammonia and argon atmospheres in 700–1200 °C temperature range. Effect of sodium carbonate (Na 2CO 3) addition on this process was investigated. Reaction products were subjected to X-ray diffraction, particle size distribution, gravimetric and Fourier transformed infrared spectroscopy analyses. Particle size and crystallite thickness of the formed hBN were seen to increase from about 60 nm and 5 nm at 700 °C to 230 nm and 19 nm at 1200 °C, respectively in NH 3 atmosphere with Na 2CO 3 addition. Highest conversion of boron in the precursor into hBN was achieved as 73.6% when Na 2CO 3 added precursor was reacted at 1200 °C in NH 3. hBN powder with high yield and relatively large particle size was obtained at low temperature such as 1200 °C with Na 2CO 3 addition. Role of Na 2CO 3 addition was suggested to be formation of a sodium borate melt from which hBN crystallized via the reaction of borate and nitrogen ions in the melt. Obtained hBN has the potential for utilization as a clean starting material for synthesis of B or N containing compounds.