Effect of N-aryl para-benzhydryl substituent on the thermal stability of α-diimine nickel catalyst.

Abstract

The thermal stability of α-diimine nickel catalysts has always been the focus of research. The introduction of large groups in the backbone or N-aryl ortho-position is a relatively mature solution. However, the question of whether the N-aryl bond rotation is a factor affecting the thermal stability of nickel catalysts is still open. In this work, the effects of N-aryl para-benzhydryl substitutes on catalyst thermal stability were investigated, and the results of ethylene polymerization and the factors affecting thermal stability (steric effect, electronic effect, five-membered coordination ring stability, N-aryl bond rotation, etc.) were systematically analysed. It is believed that the introduction of large steric hindrance groups at the N-aryl para-position hinders the rotation of the N-aryl bond. This obstacle effect is beneficial to improving catalyst thermal stability, and the obstacle capacity is weakened with the increase of ortho-substituent size. This article is protected by copyright. All rights reserved.