Abstract
Long-flame coal is a bituminous coal with the lowest metamorphic degree, accounting for 16.1% of China’s coal reserves. With increases in mining depths and intensities, mine gas disasters related to the mining of long-flame coal are becoming increasingly serious. Therefore, the exploration of the effect of moisture on the adsorption of methane in coal can provide support for popularizing the application of hydraulic measures in long-flame coal mining areas. In this paper, a molecular structure model of long-flame coal was established by molecular dynamics and the Monte Carlo method. The adsorption characteristics of methane in long-flame coal structures under different pressures were simulated, and the effects of different amounts of water on the methane adsorption and adsorption heat were explored. The results show that, under the same adsorption equilibrium pressure, the methane adsorption rate decreases with increasing water content, and with increasing adsorption equilibrium pressure, the adsorption capacity of methane increases gradually; this increasing trend is in agreement with the Langmuir equation. The water adsorption of coal is greater than the methane adsorption of coal. With the increase in the number of water molecules, when coal-based molecules adsorb methane and then adsorb water molecules, the adsorption heat of methane is reduced, and the desorption of methane molecules is promoted.
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