Abstract

The activated carbon fiber (ACF) was treated by different concentration nitric acid (HNO3) and hydrogen peroxide (H2O2) oxidization to enhance its adsorption capacity to hexavalent chromium (Cr6+) ion. The adsorption amount and adsorption kinetics of Cr6+ ion on ACFs, and the surface chemical groups were investigated. The results showed that the modified ACFs with 1% HNO3 and 10% H2O2 had a better adsorption capacity, respectively. The adsorption amount of ACFs was affected strongly solution pH value, and decreased significantly with increasing of the pH value. The adsorption kinetics indicated that the adsorption rates of Cr6+ ion on different modified ACFs were well fitted with the pseudo-second-order kinetic model. After 1% HNO3 and 10% H2O2 modification, respectively, the total acidic oxygen-containing groups on ACFs surface had an increase obviously, which might be enhance the adsorption amount of Cr6+ ion on ACFs.

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