Effect of mixed nonionic surfactants on microemulsion phase boundary, fuel property, and engine performance of biofuels

Abstract

Microemulsion biofuels can become one of alternative biodiesels using suitable nonionic surfactants and cosurfactant to emulsify vegetable oil and ethanol with the appropriate formulae. Without the further chemical improvement, the low volatility and high viscosity because of triglycerides in vegetable oil can cause a serious problem in engine operation. This work proposed a systematic investigation of microemulsion biofuel prepared from rice bran oil and ethanol using mixed nonionic surfactant systems (Dehydol LS7, Tween 80, and Span 80) as surfactant (S) and 1-octanol as a cosurfactant (C) at molar ratio of 1:30. Microemulsion phase behaviors can be examined through the ternary phase diagram of rice bran oil, ethanol, and S:C. It was observed that Dehydol LS 7 was poor in solubilization of rice bran oil and ethanol because of their preference in hydrophilic compounds rather than lipophilic compounds. Introduction of Tween 80 or Span 80 into the biofuels using Dehydol LS 7 enhanced the solubilization of these systems as the extent of single-phase boundary was significantly enlarged because of the hydrophilic–lipophilic balance of the mixture and chemical structure of surfactants. The fuel properties of microemulsion biofuel were investigated through kinematic viscosity, specific gravity, flash point, cloud point, pour point, and higher heating value. It was found that mixed surfactant also improved some fuel properties due to additional surfactants contain many oxygenated functional groups, however, some parameters were slightly substandard. The combustion characteristics and exhaust emission were investigated in CI diesel engine. It was observed that the in-cylinder pressure was lower under the combustion of microemulsion fuel mainly due to the high latent heat of vaporization of alcohols. The start of combustion was more retarded with the addition of Span 80, especially at low load condition. It was observed that the significant reduction in nitrogen oxides was achieved with the combustion of microemulsion fuel while unburnt hydrocarbon emissions were higher compared to diesel fuel. The obtained experimental data showed that microemulsion biofuels can be a promising alternative biodiesel although the individual usage in engine was slightly less efficient than commercial diesel fuel.