Effect of Minor Alloying Substitution on Glass-Forming Ability and Crystallization Behavior of a Ni<sub>57</sub>Zr<sub>22</sub>X<sub>8</sub>Nb<sub>8</sub>Al<sub>5</sub> (X = Ti, Cu) Alloy Synthesized by Mechanical Alloying

Abstract

Ni57Zr22X8Nb8Al5 (X = Ti, Cu) metallic glass (MG) and nanocomposite powders were synthesized by mechanical alloying. Outstanding differences in glass-forming ability (GFA), thermal property, particle size and crystallization behavior were found for the two synthesized alloy powders with different alloying substitutions. The Ti-containing MG powder exhibits better GFA, higher thermal stability, lower enthalpy of crystallization and smaller particle size compared with the Cu-containing nanocomposite powder, respectively. Meanwhile, the crystallization of the Ti-containing MG powder is governed by typical volume diffusion-controlled three-dimensional growth. The better GFA for the Ticontaining alloy system could be explained by appropriate atomic-size mismatch and large negative heat of mixing among main constituent elements. The higher enthalpy of crystallization for the Cu-containing nanocomposite powder leads to the lower thermal stability and larger particle size of the powder than Ti-containing MG powder. [doi:10.2320/matertrans.M2013184]