Effect of MgO, Mg-Al-NO3 LDH and calcined LDH-CO3 on chloride resistance of alkali activated fly ash and slag blends

Tao Liu,Yuxuan Chen,Qingliang Yu,Jianfeng Fan,H.J.H Brouwers

doi:10.1016/j.conbuildmat.2020.118865

Abstract

The mechanism of layered double hydroxides (LDHs) formation with the addition of magnesium oxide (MgO), the LDHs reconstruction of calcined layered double hydroxides (CLDHs) and the effect of externally added synthetic LDHs in alkali-activated materials (AAMs) system are the important factors influencing the chloride resistance of AAMs. The objective of this research is to investigate the different effects of MgO, nitrate intercalated LDH (Mg-Al-NO3 LDH) and calcined natural LDH-CO3 on the alkali activated fly ash and slag blends (AAFS) in terms of chloride resistance. Mg-Al-NO3LDH was successfully synthesized with the co-precipitation method. CLDH was also obtained by thermal treating natural Mg-Al-CO3 LDH. The reaction heat flow and reaction products of the AAFS were tested by isothermal calorimetry and X-ray diffraction (XRD), respectively. The microstructure of the AAFS was characterized by the nitrogen sorption tests (BET) and mercury intrusion porosimetry (MIP). The compressive strength of AAFS was also tested. The non-steady-state migration (NSSM) was applied to determine the chloride resistance of AAFS. The Ordinary Portland Cement (OPC) samples were also studied for comparative purpose. The results of the calorimeter test showed that the MgO, Mg-Al-NO3 LDH, and CLDH delayed the time to reach the reaction peak (TRRP) at 3.9%, 11.2%, and 9.2%, respectively. The MIP results illustrated that mesopores and micropores of AAFS were refined by the three admixtures. The NSSM results indicated that CLDH can significantly improve the chloride resistance of AAFS binder comparing to the samples containing MgO and Mg-Al-NO3 LDH. The different influences of MgO, Mg-Al-NO3 LDH and CLDH were compared in this study.

Highlights

Numerous military and civilian concrete structures exposed to the marine environment face the risk of chloride corrosion [1]
The mechanism of layered double hydroxides (LDHs) formation with the addition of magnesium oxide (MgO), the LDHs reconstruction of calcined layered double hydroxides (CLDHs) and the effect of externally added synthetic LDHs in alkali-activated materials (AAMs) system are the important factors influencing the chloride resistance of AAMs
The objective of this research is to investigate the different effects of MgO, nitrate intercalated LDH (Mg-Al-NO3 LDH) and calcined natural LDH-CO3 on the alkali activated fly ash and slag blends (AAFS) in terms of chloride resistance

Summary

Introduction

Numerous military and civilian concrete structures exposed to the marine environment face the risk of chloride corrosion [1]. Chloride penetration into reinforced concrete can cause local destruction of the passive layer, leading to localized corrosion. ⇑ Corresponding author at: Department of the Built Environment, Eindhoven. Facing a large amount of chloride ingress problems, approximately 3.4% of the global GDP ($2.5 Trillion USD) is spent each year to prevent, mitigate, and repair the infrastructure damage due to chloride-induced corrosion [2]. The corrosion problems of offshore concrete structures lead to an urgent demand for the research about the chloride resistance of the alkali activated materials (AAMs).

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