Abstract
For better understanding of the behaviors of MgO and BaO within glass frit PF798, which is a candidate for use in immobilization of radioactive nuclear waste and consisted of 63.6SiO 2 , 16.8B 2 O 3 , 4Al 2 O 3 , 3ZnO, 4.4CaO and 8.2Li 2 O in mole pct, oxidation-reduction equilibrium experiments for Fe 3+ /Fe 2+ couple were conducted with the melts of (PF798+MgO) and (PF798+BaO) at 1473 K and under a stream of pure CO 2 of 1 atm.
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