Abstract
The aim of this study is to investigate the effect of grain size on the electrical properties of Ce0.9Gd0.1O1.95-x mol% MgO (GDC-xMgO) and to evaluate them as electrolytes for use in intermediate-temperature solid oxide fuel cells (IT-SOFCs). For this purpose, GDC-xMgO (x = 0–15) electrolytes were synthesized by the glycine-nitrate process and sintered at different temperatures. Impedance spectroscopy measurements revealed that for each composition, the grain-boundary resistivity decreased with decreasing grain size for the samples with grain size of >0.4 μm. Much too small grain sizes (0.2 < dg < 0.3 μm) produced an increase in grain-boundary resistivity. The addition of MgO could weaken the influence of grain sizes on the grain-boundary resistivity. The interfacial polarization resistances could be decreased by adding MgO to GDC. The GDC-1MgO sample sintered at 1200 °C exhibited the highest total conductivity of 8.11 × 10−2 S cm−1 at 800 °C. The maximum power density of the GDC-1MgO-based cell was 0.73 W cm−2 at 800 °C, which was much higher than that of the GDC-based cell. The results indicated that the GDC-1MgO was a potential electrolyte for IT-SOFCs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
