Effect of metal oxide/alumina on catalytic deoxygentation of biofuel from physic nut residues pyrolysis

Abstract

Rapid catalytic thermal conversion of Physic nut (Jatropha curcas) residues for upgrading the released vapors was performed using analytical pyrolyzer-gas chromatography/mass spectrometry at 873 K. Conditioning of the evolved vapor product is required since the main vapor products formed without catalysts typically contained around 60% fatty acids, while the total hydrocarbon yields were only 12%. Catalysts tested were alumina (Al2O3) alone and modified by 5 wt% impregnation with various transition metal salts and then calcined to metal oxides. A significant decrease in the proportion of oxygenated compounds (including acids) from 73% without a catalyst to less than 10% with, and an increased conversion to hydrocarbons of more than 70% was obtained with the metal/Al2O3 catalysts at a Jatropha:catalyst (J:C) ratio of 1:10. The product selectivity was greatly increased as the J:C ratio was increased from 1:1 to 1:10. The total hydrocarbon selectivity of the metal/Al2O3 catalysts was increased in the order of Pd > Ni > Ce > Ru > La > none > Co > Mo, with the highest proportion of total hydrocarbons obtained being 75%. In addition, only a low yield (<2%) of polycyclic aromatic hydrocarbons was obtained from the conversion of Jatropha curcas residues. However, these catalysts adversely promoted N-containing compounds, suggesting that a further denitrogenation process is necessary. Nevertheless, the overall performance of these transition metal/Al2O3 catalysts is acceptable and they can be considered as good candidates for bio-oil upgrading.