Abstract
Initially, in the synthesis of Cu–BTC MOFs some fraction of Cu was expected to be replaced with Mg to enhance its CO2 adsorption properties. Indeed, an enhancement in the specific surface area, microporosity and CO2 adsorption capacity was observed; however, Mg was not detected. Therefore, additional syntheses of Cu–BTC MOFs with the same Cu to BTC ratios were performed but in the absence of Mg to explain the observed enhancement. It was found that the adjustment of the Cu–BTC ratio to 1.09 : 1.0, which differs from that reported in the literature, resulted in a Cu–BTC MOF with higher specific BET surface area, larger micropore volume, and consequently, superior CO2 adsorption of 9.33 mmol g−1 at 0 °C and 1 bar.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
