Effect of long-range transported fire emissions on aerosol and cloud properties at high latitudes: In situ measurements and satellite observations

Abstract

Global warming and climate change-induced rise in Earth’s temperature have increased the frequency of forest/wildfires over the past decade. Therefore, understanding the effect of fire emissions on aerosol-cloud interactions is crucial for improving Earth system models.          We present observations from in-situ measurements of aerosol properties at the Puijo SMEAR IV station in eastern Finland and the Zeppelin Observatory in Ny-Ålesund, High Arctic. Both stations are frequently inside low-level clouds due to their topographic prominence. During the autumn of 2020, fire emissions from the same active fire region in south-eastern (SE) Europe reached both stations after ~2 - 8 days of atmospheric aging. This enabled us to investigate the changes in aerosol and cloud properties for clouds formed under the influence of aged fire emissions (referred to as the ‘fire’ period) and under cleaner conditions with no fire emission influence at these stations (‘non-fire’ period). The aerosol hygroscopicity parameter (κchem) was derived from the chemical composition data obtained from online aerosol mass spectrometers and was used to derive the number concentration of cloud condensation nuclei (NCCN) from the measured particle size distributions.          At both stations, the aerosol number concentration in the accumulation mode and the cloud condensation nuclei concentration (NCCN) were higher during the fire period than during non-fire times. However, the aerosol hygroscopicity increased at Puijo but decreased a Zeppelin from the non-fire to fire period. At Puijo, in-situ measured cloud droplet number concentration (CDNC) was by a factor of ~7 higher when comparing fire to non-fire periods. This was in good agreement with the satellite observations (MODIS, Terra). At Puijo, the higher CCN concentrations during the fire period cause a depletion of the water vapor available for cloud droplet activation leading to larger observed activation diameters during cloud events despite the higher hygroscopicity of the aerosol particles.          These observations show the importance of SE European fires for enhancing the CCN activity in Finland and the high Arctic. Results from this study emphasize the complex interplay between particle size and chemical composition, and how fires even from sources far away can have strong impacts in these remote regions.