Effect of liquid surface tension data on the validity and accuracy of solid surface tension components and parameters in the application of the van Oss–Chaudhury–Good approach

Abstract

This paper studies the effects on valid domain of contact angles and error limits of solid surface tension components and parameters (SSTCPs)/square roots of SSTCPs (SQSSTCPs) from the changes in liquid surface tension components and parameters (LSTCPs) when applying the van Oss–Chaudhury–Good (vOCG) approach. The results of maximum absolute errors and maximum relative errors (MREs) in SQSSTCPs/SSTCPs, induced by errors in LSTCPs or contact angles, show that most SQSSTCPs/SSTCPs can be evaluated at moderate accuracy from the lowest condition number liquid triplets, assuming that |Δθi| = 1° and = 0.1 mN/m (i = 1, 2, 3, k = LW, +, −). This confirms the validity of the vOCG approach. The accuracy of each SQSSTSCP/SSTCP declines with increasing θi or decreasing parameter when θi > 0 or a critical value, provided the other two contact angles are kept fixed. This explains the underlying reasons for negative SQSSTCPs. At the scale proposed by vOCG, dimethyl sulphoxide is not suggested for use. Comparing with the MREs obtained at vOCG scale, considering the acidity of diiodomethane improves the accuracy of ; using the scales proposed by Lee and Shen do not affect the accuracy of SSTCPs, but using the scale proposed by Della Volpe et al. improves the accuracy of SSTCPs at low θ2 and θ3 while declines that at high ones. For a low , low surface tension apolar liquid is preferred for high accuracy. The dependence of the accuracy of SQSSTCPs/SSTCPs on contact angles suggests the importance of considering contact angle in accuracy evaluation.